Lasted one year at each.
Benfica - the team finished the Portuguese League in third place (behind rivals Porto and Sporting) and was knocked out of the Portuguese Cup in the quarter-finals (after losing to Vitória de Guimarães). This, along with an offer from PSV, sufficed for the manager to leave one year before the end of his contract, even though Benfica reached the quarter-finals of the Champions League before losing to Barcelona, who ended up winning the trophy.
PSV - In the 2006–07 season, Koeman served as head coach of PSV, as successor of Guus Hiddink. PSV dominated the first season half, putting competitors as AZ and Ajax at a reasonable distance and PSV was almost destined to become champions again. However, PSV suffered in the second half of the season, also because of injuries of players Jefferson Farfán, Alex and Ibrahim Afellay, obtaining only 19 out 39 possible points.[7] AZ and Ajax regained their momentum, making for a close finish, with all three teams tied at 72 points before the last competition day.[8] AZ played struggling Excelsior in their final match, but did not manage to win. Ajax played at Willem II, but did not score enough goals; it was PSV eventually who triumphed against all odds, winning at home 5–1 against Vitesse Arnhem, and thereby becoming Eredivisie champions on goal difference.